Structure and Properties

This subject has the following teaching availabilities in 2011:

• 610-142 Chemistry B (prior to 2009)
• 610-052 Chemistry Biomedical Science B (prior to 2008)

Students who have completed all of the following subjects may not also gain credit for this subject

• 610-210 Light, Matter and Chemical Change A (or 610-211 Light, Matter and Chemical Change B) prior to 2009
• 610-220 Organic Chemistry (or 610-221 Organic & Bio-organic Chemistry) prior to 2009
• 610-240 Inorganic and Bio-inorganic Chemistry A (or 610-241 Inorganic and Bio-inorganic Chemistry B) prior to 2009

This subject covers key concepts related to the stereochemical and electronic properties of molecules and the methods central to their study. Important elements of the subject include the spectroscopic characterisation and quantification of materials by a range of spectroscopic techniques, molecular orbital techniques and the application of approaches based on molecular symmetry and group theory to the understanding of molecular properties, stereo-selective reactions, bonding and spectroscopy. These topics have applications to advanced materials, light emitting polymers, chemical analysis and catalysis in biological and industrial systems.

Upon completion of this subject students should;

• be able to classify molecules according to their symmetry and to relate their physical properties (e.g. dipole moment, isomerism) to the molecular symmetry;
• have a basic knowledge of the basis and application of spectroscopic techniques that are conducted in the presence (NMR, EPR) or absence (IR, Raman, UV-Vis.) of an applied magnetic field;
• be able to apply molecular orbital theory to simple homo- and heteronuclear diatomic molecules and polyatomic molecules;
• be able to apply simple Hűckel approaches to arrays of atoms having orbitals of p symmetry;
• be able to identify systems that are aromatic or antiaromatic in character and to have a knowledge of their basic reactions;
• be able to describe the changes in bonding that occur to small molecules (e.g. CO) on binding to a transition metal and to be able to apply these concepts to the catalysis of reactions of those species.

Three to six short tests each of approximately 1 hour duration conducted on-line using the learning management system (LMS) for a total of 20% and a three-hour end of semester exam (80%).

• J McMurry, Organic Chemistry, Thomson Brooks/Cole, 7th Ed, 2008.
• P Atkins and J De Paula, Atkins’ Physical Chemistry, Oxford University Press, 9th Ed, 2010.
• C E Housecroft and A G Sharpe, Inorganic Chemistry, Pearson Prentice-Hall, 3rd Ed, 2008.

This subject potentially can be taken as a breadth subject component for the following courses:

• Bachelor of Arts
• Bachelor of Commerce
• Bachelor of Environments
• Bachelor of Music

You should visit learn more about breadth subjects and read the breadth requirements for your degree, and should discuss your choice with your student adviser, before deciding on your subjects.

This subject will provide students with opportunities to develop the following generic skills:

• the ability to comprehend complex concepts and effectively communicate this understanding to the scientific community and in a manner accessible to the wider community;
• the ability to analyse and solve abstract technical problems;
• the ability to connect and apply the learnt concepts to a broad range of scientific problems beyond the scope of this subject;
• an awareness of advanced technologies;
• the ability to think and reason logically;
• the ability to think critically and independently.

This subject is available for science credit to students enrolled in the BSc (both pre-2008 and new degrees), BASc or a combined BSc course.